1. Regarding the assessment for the approximate 2,600 nos. schools, it is concluded that ...
2. Regarding the assessment for the approximately 2,600 nos. schools, it is concluded that ...
Sentence 2 is correct because “approximately” is used before a number or amount, and “approximate” is used before a noun or after BE.
To understand more about how their usage varies, I suggest you look at the concordances for these two words at
www.edict.com.hk/default.htm.